Electronic Materials Science

EUGENE A. IRENE is Professor of Physical Chemistry at the University of North Carolina, Chapel Hill. He received his PhD in solid-state and physical chemistry from Rensselaer Polytechnic Institute in 1972 and worked for IBM for ten years in the Thomas J. Watson Research Center.

Preface. 1 Introduction to Electronic Materials Science. 1.1 Introduction. 1.2 Structure and Diffraction. 1.3 Defects. 1.4 Diffusion. 1.5 Phase Equilibria. 1.6 Mechanical Properties. 1.7 Electronic Structure. 1.8 Electronic Properties and Devices. 1.9 Electronic Materials Science. 2 Structure of Solids. 2.1 Introduction. 2.2 Order. 2.3 The Lattice. 2.4 Crystal Structure. 2.5 Notation. 2.6 Lattice Geometry. 2.7 The Wigner-Seitz Cell. 2.8 Crystal Structures. Related Reading. Exercises. 3 Diffraction. 3.1 Introduction. 3.2 Phase Difference and Bragg's Law. 3.3 The Scattering Problem. 3.4 Reciprocal Space, RESP. 3.5 Diffraction Techniques. 3.6 Wave Vector Representation. Related Reading. Exercises. 4 Defects in Solids. 4.1 Introduction. 4.2 Why Do Defects Form? 4.3 Point Defects. 4.4 The Statistics of Point Defects. 4.5 Line Defects-Dislocations. 4.6 Planar Defects. 4.7 Three-Dimensional Defects. Related Reading. Exercises. 5 Diffusion in Solids. 5.1 Introduction to Diffusion Equations. 5.2 Atomistic Theory of Diffusion: Fick's Laws and a Theory for the Diffusion Construct D. 5.3 Random Walk Problem. 5.4 Other Mass Transport Mechanisms. 5.5 Mathematics of Diffusion. Related Reading. Exercises. 6 Phase Equilibria. 6.1 Introduction. 6.2 The Gibbs Phase Rule. 6.3 Nucleation and Growth of Phases. Related Reading. Exercises. 7 Mechanical Properties of Solids-Elasticity. 7.1 Introduction. 7.2 Elasticity Relationships. 7.3 An Analysis of Stress by the Equation of Motion. 7.4 Hooke's Law for Pure Dilatation and Pure Shear. 7.5 Poisson's Ratio. 7.6 Relationships Among E, e, and v. 7.7 Relationships Among E, G, and n. 7.8 Resolving the Normal Forces. Related Reading. Exercises. 8 Mechanical Properties of Solids-Plasticity. 8.1 Introduction. 8.2 Plasticity Observations. 8.3 Role of Dislocations. 8.4 Deformation of Noncrystalline Materials. Related Reading. Exercises. 9 Electronic Structure of Solids. 9.1 Introduction. 9.2 Waves, Electrons, and the Wave Function. 9.3 Quantum Mechanics. 9.4 Electron Energy Band Representations. 9.5 Real Energy Band Structures. 9.6 Other Aspects of Electron Energy Band Structure. Related Reading. Exercises. 10 Electronic Properties of Materials. 10.1 Introduction. 10.2 Occupation of Electronic States. 10.3 Position of the Fermi Energy. 10.4 Electronic Properties of Metals: Conduction and Superconductivity. 10.5 Semiconductors. 10.6 Electrical Behavior of Organic Materials. Related Reading. Exercises. 11 Junctions and Devices and the Nanoscale. 11.1 Introduction. 11.2 Junctions. 11.3 Selected Devices. 11.4 Nanostructures and Nanodevices. Index.